Browsing by Author "Mguni, L.L."

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    Modulated Synthesis of a Novel Nickel-Based Metal−Organic Framework Composite Material for the Adsorptive Desulfurization of Liquid Fuels
    (Industrial & Engineering Chemistry Research, 2021) Mguni, L.L.; Yao, Y.; Ren, J.; Liu, X.; Hildebrandt, D.
    Removing sulfur from liquid fuels has become an important issue in a global society. Modulated synthesis is known to improve the crystallinity of materials, ease of handling, control of crystallite size, and degree of aggregation. A group of adsorbents [activated carbon (AC), a novel synthesized Ni-based metal–organic framework (Ni-BDC), and composites of AC@Ni-BDC treated with different concentrations of nitric acid and modulator (formic acid)] were characterized using X-ray diffractometer (XRD), high-resolution transmission electron microscopy (HR-TEM), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET), and temperature-programmed desorption (TPD)-pyridine studies. The adsorbents were also evaluated for adsorptive desulfurization. The quantities of both AC and the modulator were observed to influence the nucleation of Ni-BDC, crystallite size, and crystallinity. The adsorption activity of the composite toward thiophene (TH) was the average of the two materials (i.e., AC and Ni-BDC), while the activity doubled toward dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) with respect to the excepted average. The improved activity was attributed to enhanced pore structure, crystallinity, and synergistic effects that produced stronger acidic sites.