Chemical Engineering

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Adsorption of Chromium (VI) Using Nano-ZnO Doped Scrap Tire-Derived Activated Carbon
(Scientific Research Publication, 2022-09-27) Chigova, J. T.; Mudono, S.
Nowadays, nano mineral modified biochars show a promising adsorption capacity for pollutants removals by combining the advantages of porous structure of biochar and unique property of nano minerals. In this work, nanozinc oxide doped scrap tire derived activated carbon (nZnO-STAC) was synthesized by wetness impregnation method. Equilibrium data were analyzed using Langmuir and Freundlich isotherm models while the kinetics of the process were examined using Lagergren Pseudo-first and second order, intraparticle diffusion and Elovich kinetic models. Characterization of the activated carbon by Powder X-ray Diffraction (PXRD). The surface groups present on the activated carbon surface were determined using the Fourier Transform Infra-Red Spectroscopy (FTIR) analysis. Optimization studies were carried out to determine the effects of pH, initial metal concentration, adsorbent dosage, contact time and adsorbent particle size on the Cr (VI) removal efficiency. The results showed optimum Cr (VI) removal at pH 3, 10 mg/L concentration, 120 minutes of contact using 1000 - 1400 µm adsorbent particle size at a dosage of 2.5 g/L. The adsorbent structure was found to be predominantly amorphous. The chromium removal efficiency of the adsorbent was around 81.6%. Of the tested kinetic models, the pseudo-second order model exhibited the best fit with the experimental data with an R2 value of 0.9744. This study clearly demonstrates the feasibility of using the nano-ZnO doped scrap tyre derived activated carbon adsorbent for the remediation of chromium (VI) polluted industrial wastewaters.
Adsorption of Mercury by Pterocarpus Anglolensis: Study on Adsorption Isotherms and Kinetics
(Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR, 2022) Mapombere, Garainesu; Nyoni, Bothwell; Sibali, Linda L.; Chiririwa, Haleden; Seodigeng, Tumisang
The efficiency of Pterocarpus Anglolensis sawdust, an abundantly available waste product of the timber industry, capacity as an adsorbent for mercury was investigated. A series of batch experiments was carried out with experimental conditions of metal concentration, adsorbent concentration, pH, and contact time being changed. The concentration of the metal ion was deduced using spectrophotometric means. The adsorption efficiency was found to be pH-dependent with pH 4 being the optimum. 90 minutes was found to be the equilibrium time with particle size range 90-124 μm being the most efficient. Maximum adsorption of mercury was evaluated at 80.33 %. The experimental data was best modeled by the Freundlich isotherm and Pseudo second-order kinetic models. The calculated adsorption parameters are Kf = 0.0002 L/mg, bF = 3.0 and k2 = 0.00016 g/μg.min.
An attainable region approach for the recovery of iron and zinc from electric arc furnace dust
(2019) M.C. Siamea, M. C.; Kaomab, J.; Hlabanganac, N; Danhad, G.
This study investigated the application of the attainable region optimization technique to establish the optimum hybrid hydrometallurgical and pyro-metallurgical process conditions required to treat the electric arc furnace dust. The analysis of the results obtained showed that a combination of an agitation speed of 800 rpm, sodium hydroxide concentration of 8.0 mol/L and a leaching temperature of 80 °C were the optimum conditions for the hydrometallurgical process, while a roasting temperature of 1200 °C, carbon content of 35.27% and a roasting period of 36 h were the optimum conditions for the pyro-metallurgical process. The iron recovered from the dust was recycled in order to upgrade the iron content of the electric arc furnace charge, thereby reducing both process loses and process wastes.
An attainable region approach for the recovery of iron and zinc from electric arc furnace dust
(2019) Siame, M.C.; Kaoma, J.; Hlabangana, N.; Danha, G.
This study investigated the application of the attainable region optimization technique to establish the optimum hybrid hydrometallurgical and pyro-metallurgical process conditions required to treat the electric arc furnace dust. The analysis of the results obtained showed that a combination of an agitation speed of 800 rpm, sodium hydroxide concentration of 8.0 mol/L and a leaching temperature of 80 °C were the optimum conditions for the hydrometallurgical process, while a roasting temperature of 1200 °C, carbon content of 35.27% and a roasting period of 36 h were the optimum conditions for the pyro-metallurgical process. The iron recovered from the dust was recycled in order to upgrade the iron content of the electric arc furnace charge, thereby reducing both process loses and process wastes.
Application of amine-modified tannins gels as coagulants in wastewater treatment
(Research Square, 2024-08-28) Thelmmer, M.; Ncube, S.; Moyo, L.B.; Mamvura, T.A.; Danha, G.; Simate, G.S.; Tshuma, N.
Tannin (T) is an organic substance that may potentially be used as an inexpensive, environmentally friendly, and effective bio-coagulant to remove impurities from residential and commercial wastewater. In this study, bio-coagulants were prepared using tannins obtained from the wattle tree (Acacia mearnsii). The bio-coagulants were modified using formalin and optionally, ethanolamine (ETA) and ammonium chloride (NH 4 Cl) as amine sources through the Mannich Reaction scheme. Three coagulants were prepared, T-ETA modified tannin, T-NH 4 Cl modified tannin and a mixture of T-ETA: T-NH 4 Cl in molar ratio 1: 1. Aluminium sulphate [Al 2 (SO 4) 3], a metal-coagulant was also used as the standard for comparison. The three coagulants were tested at varied concentrations (500–1250 mg/L) using jar tests on laundry wastewater to see their effect on remediation of wastewater. A mixture of bio-coagulant T-NH 4 Cl and T-ETA was most effective with highest removal efficiencies for turbidity (94%), COD (85%), Total solids (87%) and nitrates (99%). For colour removal T-NH 4 Cl modified tannin showed the highest removal efficiency of 92%. The results support the use of cheaper and environmentally friendly amine modified tannin-based flocculants in laundry wastewater treatment as they showed less toxicity on the treated water.
Beverage Effluent Treatment Technology
(2016) Tshuma. J.; Maqhuzu, A.; Bhebhe, S.; Mudon, S.; Kaitano, H.; Mashanga, D.; Mpofu, C.; Tshuma, I.; Mkandla, C.K.
A detailed beverage effluent treatment technology was developed in a period of 4 months, using samples from an operating beverage plant. The total number of samples collected were 1304. The volume of the sample collected hourly was 500ml for 4 hours to give a composite sample. The plant operated continuously for 6 days a week and had two-12 hour shifts a day. The technology consisted of four water treatment methods combined consecutively which were chemical, physical, biological and physical treatment methods. The aim of developing the technology was to reduce the sCOD, TSS and pH parameters to the required environmental specification. The untreated beverage wastewater has high solids content, high organic matter, and low pH which need pretreatment before it is discharged into the municipal sewage treatment works. The developed technology reduced the high solid content, high organic load and adjusted the pH to the required Bulawayo Municipality environmental specifications. The average percentage reduction in sCOD and TSS was 91.1% and 90.6% respectively. The pH was adjusted to 8.05. The obtained results indicated that the developed technology was effective for treating beverage wastewater at ambient temperature to meet the quality of effluent that can be discharged into public water works.
Biological acidification of pig manure using banana peel waste to improve the dissolution of particulate phosphorus: A critical step for maximum phosphorus recovery as struvite
(Heliyon, 2022-07-22) Moyo, L.B.; Simate, G.S.; Mutsatsa, T.
Traditional disposal of agricultural bio-waste such as pig manure and banana peel waste poses an environmental nuisance. The uncontrolled disintegration of these waste materials decomposes to toxic effluent and methane a greenhouse gas twenty-one times more potent than carbon dioxide at trapping heat in the atmosphere, which is detrimental to the climate by elevating temperatures. Agricultural bio-waste is rich in nutrients that include nitrogen and phosphorus. Selectively separating these nutrients from the solid phase to produce high value products has been envisaged as an effective method of waste valorisation. This study aims to investigate the solubilisation of phosphorus (P) during anaerobic digestion (AD) of pig manure with banana peel waste as the co-substrate. The objective was to enhance the biological dissolution of the phosphorus from solid pig manure to the aqueous phase as this is envisaged to subsequently ease the recovery of P as a concentrated product via crystallization. Thereafter, phosphorus is used as a slow-release mineral fertilizer. Biological acidification was effective in reducing the pH to less than 6.50 from an initial pH of 7.28 at higher doses of BPW >100 g/L. Maximum dissolution of total phosphorus of 75% was observed at a pH of 5.40. Multiple regression analysis was used to correlate pH, banana peel waste concentration, and the anaerobic digestion time (ADT) to optimize the dissolution of P as this was deduced to be occurring at a low pH. A 2nd order polynomial was deduced to best fit the data with an R2 value of 0.90. The p values for the HRT and banana peel waste concentration were both <0.05 showing that both variables had a strong influence on the pH.
Challenges and Drivers of Industrialist Propensity Among Chemical Engineering Students in STEM Institution in Zimbabwe: Towards A Conceptual Framework
(International Journal of Environment, Engineering and Education, 2024-04-24) Nkala, B.; Sibanda, V. M.; Ndhlovu, J.; Hobane, L.; Singh, S
NUST in Zimbabwe grapples with a significant challenge. Despite enrolling many students in chemical engineering, the nation lacks operational industries. Consequently, graduates often encounter difficulties securing employment or attachment placements post-graduation. This underscores the critical need to foster student entrepreneurship, encouraging innovation and idea generation. The study employed a mixed-methods research design to address this issue, combining qualitative and quantitative methodologies. The quantitative aspect utilized a quasi- experimental pre-test and post-test design, while the qualitative component involved conducting focus group interviews with chemical engineering students in the experimental group. The findings from both approaches complemented each other, providing a comprehensive understanding of the factors influencing entrepreneurial propensity among NUST chemical engineering students. Data collection involved distributing research instruments and questionnaires to NUST students and individuals associated with the mining and pharmaceutical industries. The collected data were then entered into an Excel spreadsheet, allowing for the recording of respondents' numbers alongside their respective responses. The study applied descriptive statistics to evaluate responses and their alignment with research objectives, revealing barriers to entrepreneurial inclination among NUST chemical engineering students, such as limited resources, risk aversion, inadequate entrepreneurial education, and cultural norms. Students benefited from personal motivation, a supportive educational atmosphere, networking opportunities, and exposure to innovative ideas. These factors nurtured self-determination, social networking, and an entrepreneurial mindset. To foster entrepreneurial spirit among NUST chemical engineering students, the study suggests educational reforms, mentorship programs, and potential policy changes create an enabling environment, empowering students to pursue entrepreneurship and contribute to economic growth.
Characterization, kinetics and thermodynamic evaluation of struvite produced using ferrochrome slag as a magnesium source
(South African Journal of Chemical Engineering, 2023-10-24) Moyo, L.B.; Simate, G.S.; Hobane, N.; Dube, C.
There is limited data on studies that have focused on the kinetics, thermodynamics, and characterization of struvite crystallization from alternative magnesium sources. This study focused on thermal analysis of struvite (produced using ferrochrome slag as a magnesium source) and the results indicated that the residual quantities of struvite were lower than the theoretical mass loss of struvite of 51.42%. When using ferrochrome slag (FCS) as the magnesium source, 47.9%, 47.4%, and 46.9% losses in mass were observed for heating rates of 5◦C/min; 10◦C/min and 15◦C/min respectively. The mean activation energies for struvite produced using FCS were deduced using isoconversional kinetic methods and ranged from 49.81to 56.20 kJ/mol which is very similar to the activation energies deduced using MgCl2. The study also focused on the surface morphology, and particle size of the final product at different pH and N:P ratios. The final particle size distribution of the product was significantly influenced by the solution pH. To improve the crystal growth kinetics for both MgCl2 and FCS, a high ratio of N:P molar ratios should be adopted. The product's highest median particle size was obtained using FCS as the magnesium source at a low pH. Median particle size increased with decrease in pH, at a pH of 7.5 the recorded median particle size was 96 µ m whilst, the lowest was 31 µ m at a pH of 9.5. The highest percent of fines (<10 µ m) was recorded at a pH of 9.5 using FCS as magnesium source in the metastable region of struvite precipitation whereas at a pH of 7.5 no fines (<10 µ m) were recorded. SEM images confirmed that the struvite underwent morphological changes when prepared with FCS in comparison to that produced using MgCl2. The surface morphology of the finished product demonstrated the presence of irregular shaped particles, due to presence of impurities. The kinetic data showed that struvite precipitation was limited by the chemical reaction step. Model fitting was used to determine the reaction control mechanism and the average activation energies obtained by four model free methods were FWO (56.2), KAS (51.67) Starink (49.61) and Tang (49.81) kJ/mol, indicating that the FWO method was the least accurate method. The thermodynamic data indicated that the thermal degradation of struvite crystals has a high degree of disorder, and the process is endothermic, irreversible, and non-spontaneous.
Determining an optimal interstitial filling condition: An Attainable Region approach
(Elsevier, 2018) Hlabangana, N.; Madiba, M.S.; Bhondayi, C.; Mguni, Nonhlanhla G.; Danha, Gwiranai
In this article, we present yet another application of the Attainable Region (AR) method to data from a laboratory scale milling of a low grade gold ore. In this particular case, we investigate how to optimize the amount of material in a desired size class for a scenario where the boundaries of the desired size class of interest are changed. The AR approach has never been applied in such a scenario before. Using a mono sized feed of − 1700 + 850 μm, two desired product size classes of interest (− 850 + 150 μm and − 150 + 75 μm) are selected in order to determine the optimum interstitial filling (U) to be used in the mill. Two different values of U, 1.75 and 1.0 respectively, are obtained as optimal. Our results also show that optimal operating conditions are different for different objective functions. We demonstrate that the AR may be used to specify optimal conditions that may be used for particle size reduction processes. We also illustrate how an AR boundary for optimization purposes can in certain cases be extended using the ‘mixing principle’.
Determining Optimum Wet Milling and Leaching Parameters for Maximum Recovery of Gold
(Research Publish Journals, 2017-12) Mguni, Nonhlanhla G.; Bhebhe, Siboniwe; Danha, Gwiranai; Tshuma, Joel; Hlabangana, N.
Abstract: The comminution and leaching unit operations play a vital role in the extraction process of valuable minerals from ores. Historical research efforts have focused more on optimizing these two unit operations individually rather than as an entire integrated process. The approach employed in modern day research is now driven by the process intensification philosophy. Process intensification detects that developing an integrated approach to mineral processing systems and flow sheets leads to improved efficiency of the overall process and can help attain optimum recovery and a reduction in energy and material costs. In this article, we present laboratory scale batch grinding and leaching profiles of a mono-sized gold ore sample (-1700 + 850 μm). The sample was obtained from a run-of-mine (ROM) ore of one the leading gold processing plants in South Africa. Various combinations of grinding media fill level and ball size were investigated, showing that breakage is more pronounced for the larger ball sizes tested. We also found that using a higher media filling (J = 30%) and a larger media size (30 mm) consumed more energy with less gold recovered during a 24 hour leaching period, compared to when a smaller J of 15% and 20 mm media was used. Our results show that efficient application of energy is vital and maximum profit is a complex function of energy usage and particle size. Keywords: gold, Historical research, mineral processing, energy, material costs.
Effect of ball and feed particle size distribution on the milling efficiency of a ball mill: An attainable region approach
(Elsevier, 2018-02-09) Hlabangana, N.; Danha, Gwiranai; Muzenda, E
In this article, alternative forms of optimizing the milling efficiency of a laboratory scale ball mill by varying the grinding media size distribution and the feed material particle size distribution were investigated. Silica ore was used as the test material. The experimental parameters that were kept constant in this investigation was the grinding media filling, powder filling and the mill rotational speed. The data obtained from these batch tests was then analyzed using a model free technique called the Attainable Region method. This analysis technique showed that the required product fineness is a function of grinding media and feed material size distributions. It was also observed from the experimental results that in order to increase the milling efficiency of a ball mill, towards optimum production of material in the desired size class, there is a need to correlate the ball size and the feed size distributions
Effect of ball and feed particle size distribution on the milling efficiency of a ball mill: An attainable region approach
(2018) Hlabangana, N.; Danha, G.; Muzenda, E.
In this article, alternative forms of optimizing the milling efficiency of a laboratory scale ball mill by varying the grinding media size distribution and the feed material particle size distribution were investigated. Silica ore was used as the test material. The experimental parameters that were kept constant in this investigation was the grinding media filling, powder filling and the mill rotational speed. The data obtained from these batch tests was then analyzed using a model free technique called the Attainable Region method. This analysis technique showed that the required product fineness is a function of grinding media and feed material size distributions. It was also observed from the experimental results that in order to increase the milling efficiency of a ball mill, towards optimum production of material in the desired size class, there is a need to correlate the ball size and the feed size distributions.
Effect of frother and depressant interaction on flotation of Great Dyke PGM ore.
(The Southern African Institute of Mining and Metallurgy., 2018-01) Mberi, T.; Mguni, Liberty.L; Ntuli, Freeman
In the optimization of platinum group metal flotation plants, various parameters are considered in order to achieve the desired recovery and grade of the precious metals. There should be a balance in the operating parameters so as to produce a high-grade valuable mineral concentrate without compromising recovery. This project seeks to investigate the individual and interactive effect of flotation reagents at different dosages, using a full factorial experimental design approach with two factors at six levels. Laboratory tests were conducted to illustrate the effect of frother and depressant on flotation. The results were analysed using SPSS and MiniTab. Based on the F-test at 95% confidence level, the frother had no significant effect on the concentrate grade but had a significant effect on 4E recovery, mass pull, and water recovery. The depressant had a significant effect on concentrate grade, water recovery, and mass pull. The interactive effect of frother and depressant had significant negative effect on all responses except concentrate grade. The optimum levels for recovery and grade were analysed assuming equal importance of grade and recovery as well as double importance for grade.
Effect of media shape on particle breakage in a batch ball mill: Lessons learnt from population balance model and attainable region technique. Procedia Manufacturing, 35.
(Elsevier, 2019) Khumalo, S.; Hlabangana, N.; Danha, G.; Muzenda, E
The batch grinding equation and the Attainable region technique tools were used in evaluating data obtained from the breakage of quartz ore in a laboratory batch ball mill. Using the same milling conditions and grinding equipment, test results were evaluated through the breakage distributions of different size fractions. Results prove that mixing different grinding media increases volume of grinding zones and that translates to an improvement in grinding kinetics and amount of required PSD. The tools are valuable and practical ways of evaluating the breakage of materials on the size fractional base and results of which can be used in the mathematical modelling and optimising of ball milling unit operations.
Extraction of magnesium from chrome slag by sulphiric acid leaching at low temperatures
(Novateur, 2018-11) Dube, Samukeliso; Tshuma, Bret; Jele, Thabisile B; Nkompilo, Sikhulile; Tshuma, Lawrencia; Moyo, Langa B; Hlabangana, Nkosikhona; Nkomo, Fortune; Ncube, Phendukani
In this this article ,a solvent extraction method by using sulphuric acid leaching was developed .The process conditions and parameters of sulphuric acid concentration ,leaching temperature ,leaching time and solid to liquid ratio were studied. These studied conditions and parameters were varied from 0.5M to 5M at 0.5 M interval, 30oC to 60oC at 5oC interval and 30 minutes to 240 minutes at 30 minute interval respectively. The solid to liquid ratios used were 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10.The optimum percentage extraction efficiency of magnesium as found to be 66.87% at optimum operating conditions of 4M sulphuric acid concentration 60oC leaching temperature, 120 minutes leaching time and 1:2 solid to liquid ratio.
Imaging Ellipsometry Study on the effect of Electrolyte on the drainage of an Aqueous Film trapped between a Plane Hydrophilic Silica Surface and an approaching Organic droplet
(Sadguru publications, 2014) Kuipa, Olga; Kuipa, Pardon K.
An imaging ellipsometer is used to study the drainage of an aqueous film trapped between a hydrophilic silica equilateral prism surface and a heptane or butylacetate droplet. The interfacial droplet profile on approach to the hydrophilic silica surface is such that the droplet is dimpled at its center with the periphery of the droplet (the barrier ring) being the region of closest approach to the hydrophilic silica surface. The time it takes for these drops to either achieve an equilibrium film thickness at the barrier ring or to coalesce with the macroscopic hydrophilic silica surface was experimentally determined; drainage time increases whilst equilibrium film thickness decreases with increasing salt concentration in the continuous phase. The increase in drainage time is attributed to hindered drainage of the aqueous film due probably to an increase in the aqueous film viscosity, which should translate into a decrease in the film elasticity. Compression of the double layer may also qualitatively explain the observed decrease in equilibrium film thickness at the barrier ring as the salt concentration increases. When aluminum chloride is used as the electrolyte the equilibrium film thickness is relatively constant (around 90 ± 10 nm) for the range of concentrations studied. This may be due to the fact that the aluminum ion has a valence of three and may screen electrostatic interactions between the oil droplet and the hydrophilic silica surface at relatively lower aluminum chloride concentrations.
Investigating the feasibility of using agricultural waste as an adsorbent of gold ions in small scale gold processing plants.
(2019) Tapfuma, A.; Chakawa, D.P.; Moyo, L.B.; Hlabangana, N.;; Danha, G.; Muzenda, E.
The recovery of precious metals like gold is increasing each day due to its high market prices along with diverse applications. Bio-sorption represents a biotechnological innovation as well as a cost effective and excellent tool for recovery of precious metals from aqueous solutions. This study offers an overview of a recent scenario of bio-sorption studies carried out on the use of some promising bio-sorbents which could serve as an economical means for recovering gold for small scale gold processing plants. Results show that activated carbon (control) has the highest adsorption efficiency since it contains more active site on the carbon molecules. The activated maize corn cob had the highest adsorption efficiency (77.09%) compared to all other agricultural adsorbents. Banana peels showed a significant adsorption efficiency of 56.87%.
Investigation on the Potential Production of Diesel from Waste Tires
(Scientific Research Publishing, 2022-10-24) Mudono, S.; Jim, N.; Chigova, J.T.
An alternative fuel production was performed by catalytic-pyrolysis of waste tires under a nitrogen (N2) environment and with a zeolite catalyst. Pyrolysis of scrap tires has been pointed out as an alternative to the incorrect disposal of tire wastes. Pyrolysis processes can produce tire-derived oils that may be used as fuel or added to conventional fuels, producing fuel blends with improved properties and reduced cost. The pyrolysis process can contribute to removing tire residues from inadequate sites and it can be a sustainable process to produce alternative fuels. The project investigated the conversion of the waste tires into diesel as one way of waste management and also as a viable process which in turn helps to meet the fuel demand. Uses of the diesel and the by-products from the process were also outlined. Experiments were conducted on the pyrolysis process in order to find the optimum conditions for producing the diesel through pyrolysis; the temperature and residence time were optimized in order to get maximum output from the process. The optimum temperature of the reaction was found to be 520˚C and the optimum residence time was 92.5 minutes. Quality tests of the product were then conducted on the obtained product and most of the properties were found to meet the required standard specifications. The most critical properties which are density, final boiling point, flash point and kinematic viscosity, were found to be 0.8495 g/cm3 , 370˚C, 50.5˚C and 3.681 cSt, respectively, and they were within the required specifications. Quality analysis showed that a quality product that is suitable for automobiles could be obtained from the process. The process also produces useful by- products such as char, which can aid in the purification process of the diesel after conversion to activated carbon. The process is environmentally friendly if the appropriate pollution prevention methods like gas absorption are thoroughly implemented. Waste tires are an alternative source of diesel and hence the feasibility of implementing the project on a large scale.
Kinetic and Equilibrium Modelling of Lead, Zinc and Copper Ions Sorption from Aqueous Solution Using Charcoal Fines
(ournal of Applied Science and Technology (AJAST), 2024-06-30) Mungwari, C.P.; Chipangura, W.; Ndlovu, B.; Madziwa, T.N.; Simende, C.K.; Nyenyayi, K.; Chewu, C.C.
The potential of chemically modified charcoal fines UCF (unmodified charcoal fine) and MCF (modified charcoal fines) as low cost adsorbents for the removal of Pb2+, Cu2+ and Zn2+ ions from aqueous solution was studied. MCF was prepared by chemical modification of UCF with HNO3 and KOH followed by pyrolysis. The factors influenced the effectiveness of biosorption process were pH, contact time, initial metal concentration, temperature and adsorbent dosage. FT–IR spectra confirmed the existence and interaction of the adsorbents with the effluent pollutants. MCF exhibited optimum pH, temperature, contact time, initial metal ion concentration and biosorbent dosage values of 5, 35 0C, 90 minutes, 15 mg/L and 2 g, respectively. UCF exhibited optimum pH, temperature, contact time, initial metal ion concentration and biosorbent dosage values of 6, 35 0C, 100 minutes, 20 mg/L and 2.5 g, respectively. The adsorption isotherm modelling using both adsorbents showed that the equilibrium data conformed more to Langmuir than the Freundlich model. Kinetic studies showed that the adsorption processes followed a pseudo-second order kinetic model. Thermodynamic studies confirmed the spontaneity and feasibility of the adsorption process. The results showed that both adsorbent have the potential to be applied as alternative low cost biosorbent.

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