New routes to the preparation of [ru3(co)12], [h4ru4(co)12], [rucl2(pph3)3] and [rucl2(cod)]n from anglo platinum refinery
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Date
2013
Authors
Journal Title
Journal ISSN
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Publisher
Zimbabwe Journal of Science and Technology
Abstract
New and improved routes for the preparation of ruthenium complexes are described. [Ru3(CO)12], [H4Ru4(CO)12], [RuCl2(PPh3)3] and [RuCl2(COD)]n have been prepared from [(NH4)2RuCl6] and [H2RuCl6]. Traditionally these ruthenium complexes have been prepared from commercially available RuCl3.3H2O, but here we describe their preparation from refinery materials.
Description
Journal Article
Keywords
Ruthenium complexes, Ruthenium trichloride trihydrate, Refinery materials, Ammonium hexachlororuthenate, Dihydrogen hexachlororuthenate
Citation
Chiririwa, H. & Moss, J.R., 2013. New Routes to The Preparation of [ Ru 3 ( CO ) 12 ], [ H 4 Ru 4 ( CO ) 12 ], Materials. Zimbabwe Journal of Science and Technology, 8, pp.1–8.