Assessing the impact of coal mining activities on soils and terrestrial organisms using land snail Achatina fulica as a bioindicator

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2022
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A lack of evaluation of soil quality in Zimbabwe's coal mining regions threatens the soil's ability to support biological productivity. Reports from the Environmental Management Agency of Zimbabwe and the Centre for Natural Resources Governance showed that the river (Deka) that flows through the study area was polluted. Pollutants in the Deka River were possibly emanating from land, but there was no scientific evidence. Hence it was important to evaluate pollution on land in the coal mining area. The biochemical response of the land snail Achatina fulica, exposed to soils collected from the coal mining area, was used to assess soil health. The level of selected heavy metals and polyaromatic hydrocarbon (PAH) levels were determined in soil samples obtained from 7 different sites at a coal mining area over a 2-year period (2018 to 2019). Soils obtained from the coal mining area were used to expose land snails acquired from a comparatively pure environment and acclimated to laboratory settings (for 1 year). The coal mining region's soils were determined to be mildly acidic (pH 5.53). Solubility of some metal elements increases when soils are acidic thus making such metals bioavailable and possibly increasing metal toxicity. The concentrations of heavy metals in soil samples from the coal mining area were significantly higher than in control soils (p < 0.05). The concentrations of zinc and cadmium were found to be above the World Health Organisation maximum permissible limits of 50 and 0.8 mg/kg respectively in the study period. Zinc and cadmium had mean concentrations of 164.40±81.82 and 0.97±0.27 mg/kg respectively. Results of regression analysis indicated that cadmium, lead and zinc were highly bioaccumulated with regression coefficients of 0.90, 0.94 and 0.95 respectively. Metallothionein induction in snail tissue often happen upon exposure of snails to certain metals such as cadmium. The highest levels of metallothioneins were observed in snail tissue exposed to soils with the highest concentration of heavy metal levels. The concentrations of naphthalene, acenaphthene, phenanthrene, anthracene, flouranthene, pyrene, benzo(k)fluoranthene, benzo(a)pyrene and indeno(1,2,3-c,d)pyrene in soils from the thermal power plant area were higher compared to soil from the control site (p < 0.05). High molecular weight (HMW) polycyclic aromatic hydrocarbons were predominant in soil samples from the coal mining area compared to low molecular weight polyaromatic hydrocarbons. High molecular weight polyaromatic hydrocarbons are carcinogenic and benzo(a)pyrene is the most potent. The thermal power plant area had the highest proportion of HMW polyaromatic hydrocarbons thus organisms around the area were likely to be at high risk of cancer and mutations. The sum of 14 polyaromatic hydrocarbons (Σ14 PAHs) at all sites was significantly higher than the 1000 µg/kg allowable in soil by United States Environmental Protection Agency. The ratio of anthracene to the sum of anthracene and phenanthrene was above 1 in soils from the disused coal processing area (Site C), active coal processing area (Site E) and thermal power plant area (Site F). This indicated that polyaromatic hydrocarbons in soils from Site C, E and F mostly emanated from wood, grass and coal combustion. There was a general increase in heavy metal and PAH levels from 2018 to 2019. This was probably because the study area is semi-arid hence leaching and runoff was minimal in soils from the coal mining area. Antioxidant enzyme (superoxide dismutase, catalase, glutathione peroxidase and NAD(P)H quinone reductase) and xenobiotic metabolising enzyme (glutathione S-transferase and ethoxyresorufin O-deethylase) activities were significantly increased in snails exposed to soils from the coal mining area compared to the control soil (p < 0.05). The high antioxidant enzyme activities showed that the snails were adapting to the effects of reactive oxygen species or experiencing oxidative stress. The highest xenobiotic metabolising enzyme activities were observed in snails exposed to soil from the coal tailing and power plant area. Persistent exposure (45 days) of land snails to contaminated soils markedly increased biomarker responses in land snails. Results showed ii that land snails are sensitive bioindicators and may be used to monitor pollution on land. Further more, results showed that combining biomarker measurements and chemical analysis can be a useful approach in evaluating the health of invertebrates in terrestrial ecosystems and the soil quality. The data obtained in this study can be included in soil ecotoxicological data and used in formulating soil quality management frameworks of the area.
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Ndebele D. (2022) Assessing the impact of coal mining activities on soils and terrestrial organisms using land snail Achatina fulica as a bioindicator [M.Phl. thesis]. - Bulawayo: National University of Science and Technology]